![](https://static.wixstatic.com/media/3e6543_474a8875204e45279b8c26bfe2e2b4aa~mv2.png/v1/fill/w_477,h_301,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_474a8875204e45279b8c26bfe2e2b4aa~mv2.png)
EPR
The schematic of the EPR system (left) with a vector network analyzer (VNA), an RF interferometer (two power dividers (PD), a phase shifter (Ï•), an attenuator (R) and testing device, which can be a microwave resonator (MR) or a meandered-microstrip line (MML)), an electromagnet, and a PC for control.
![](https://static.wixstatic.com/media/3e6543_5c81c30814a64cb5823a1f9187c4f75e~mv2_d_3183_2346_s_2.jpg/v1/fill/w_404,h_298,al_c,q_80,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_5c81c30814a64cb5823a1f9187c4f75e~mv2_d_3183_2346_s_2.jpg)
An experiment setup of the EPR testing system with an RF interferometer and a VNA
![](https://static.wixstatic.com/media/3e6543_249215f4170c46e896eee863dff291c7~mv2.jpg/v1/fill/w_404,h_304,al_c,q_80,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_249215f4170c46e896eee863dff291c7~mv2.jpg)
Automatic ESR measurements, including sensitivity and frequency tuning
![](https://static.wixstatic.com/media/3e6543_ec912c1cbca8419a85710c0dd06b8cb6~mv2_d_3312_2461_s_4_2.jpg/v1/fill/w_430,h_214,al_c,q_80,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_ec912c1cbca8419a85710c0dd06b8cb6~mv2_d_3312_2461_s_4_2.jpg)
Measuring 0.2 μg 2,2-diphenyl-1-picrylhydrazyl (DPPH) with a microwave resonator (MR)
![](https://static.wixstatic.com/media/3e6543_37d0a79ef1514edf9475cc399aa003de~mv2.png/v1/fill/w_384,h_120,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_37d0a79ef1514edf9475cc399aa003de~mv2.png)
![](https://static.wixstatic.com/media/3e6543_da864e208e0342249c8d23d66582eb19~mv2.png/v1/fill/w_369,h_116,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_da864e208e0342249c8d23d66582eb19~mv2.png)
Measure ESR spectrum of 0.2 μg DPPH with an MR at 7.6 GHz. Signals Δ|S21|min and Δf are absorption and dispersion ESR responses, respectively
![](https://static.wixstatic.com/media/3e6543_e79a9f090c384bf2b02626694c4af680~mv2_d_2128_1596_s_2.jpg/v1/crop/x_639,y_0,w_1489,h_790/fill/w_431,h_214,al_c,q_80,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_e79a9f090c384bf2b02626694c4af680~mv2_d_2128_1596_s_2.jpg)
Measuring 6 μg 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPOL) crystal with a broadband meander line (MML)
![](https://static.wixstatic.com/media/3e6543_48d898add5ee46b1862961ba50a4fe01~mv2.png/v1/fill/w_443,h_139,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_48d898add5ee46b1862961ba50a4fe01~mv2.png)
![](https://static.wixstatic.com/media/3e6543_0c6ab17424db474b834e1baad113fc59~mv2.png/v1/fill/w_428,h_134,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_0c6ab17424db474b834e1baad113fc59~mv2.png)
Measure ESR spectrum of 6 μg DPPH with the MML at 12.3 GHz. Signals Δ|S21|min and Δf are absorption and dispersion ESR responses, respectively.
Multi scan operation
Multi-scan operation can significantly improve ESR signal-to-noise-ratio (SNR).
N = 1
![](https://static.wixstatic.com/media/3e6543_12da669d5ba8433ba89bbf5b694f63b6~mv2.png/v1/fill/w_285,h_214,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_12da669d5ba8433ba89bbf5b694f63b6~mv2.png)
![](https://static.wixstatic.com/media/3e6543_8d2bc9aa3c134f979ef75fdb10f899e5~mv2.png/v1/fill/w_285,h_214,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_8d2bc9aa3c134f979ef75fdb10f899e5~mv2.png)
N = 100
![](https://static.wixstatic.com/media/3e6543_416ef7e80b704dd2b0eacce5f2bf9cb2~mv2.png/v1/fill/w_286,h_215,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_416ef7e80b704dd2b0eacce5f2bf9cb2~mv2.png)
![](https://static.wixstatic.com/media/3e6543_f1f2bd748c3f456dbddc5a3b7184afc0~mv2.png/v1/fill/w_293,h_220,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_f1f2bd748c3f456dbddc5a3b7184afc0~mv2.png)
N = 200
![](https://static.wixstatic.com/media/3e6543_53c7ea1406e34a39a8e8d5747606b654~mv2.png/v1/fill/w_287,h_215,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_53c7ea1406e34a39a8e8d5747606b654~mv2.png)
![](https://static.wixstatic.com/media/3e6543_565b9aca231e418c8c02c9ac2c5b0844~mv2.png/v1/fill/w_287,h_215,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_565b9aca231e418c8c02c9ac2c5b0844~mv2.png)
Absorption and dispersion ESR signals from a 0.2 μg TEMPOL crystal on a meandered microstrip line (MML) with different number of measurements N = 1, 100 and 200.
SNR vs. N
![](https://static.wixstatic.com/media/3e6543_2e56bda0f3594eae9d28c9ad2060702b~mv2.png/v1/fill/w_278,h_208,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_2e56bda0f3594eae9d28c9ad2060702b~mv2.png)
![](https://static.wixstatic.com/media/3e6543_1670ec6e500d4b66bc3ee11692536692~mv2.png/v1/fill/w_275,h_206,al_c,q_85,usm_0.66_1.00_0.01,enc_avif,quality_auto/3e6543_1670ec6e500d4b66bc3ee11692536692~mv2.png)
Measured SNR vs. N for both absorption and dispersion signals